Determination of Total Mercury in Solid Samples by Anodic Stripping Voltammetry
نویسندگان
چکیده
The anodic stripping voltammetry (ASV) was investigated to determine total mercury in solid samples using a gold electrode. deposited on the electrode preconcentration step. oxidation peak of irreversible. optimal conditions procedure were found be as follows: 0.05 mol L?1 HCl solution, deposition potential ?0.5 V vs. Ag/AgCl/KCls, time 40 s, and sweep rate 0.04 s?1. Under conditions, current showed linear dependence Hg2+ concentration range from 0.01 0.1 mg l?1. detection limit quantification 4.28 µg 12.98 L?1, respectively. mean recovery relative standard deviation 91.2% 2.4% (n = 9). successfully applied for determining collected Hanoi light bulb warehouse—The Rang Dong Light Source Vacuum Flask JSC. results compared with cold vapor atomic absorption spectrometry (CV-AAS).
منابع مشابه
Simultaneous determination of lead, cadmium, copper and zinc in Infant formula by anodic stripping voltammetry
Determination of trace elements in food is of great importance, as some of them have nutritional significance, whilst others are toxic. Long-term exposure to low levels of toxic metals could be important, especially in relation to children. Differential Pulse Anodic Stripping Voltammetry (DPASV) is applied to simultaneous determination of lead, cadmium, copper and zinc in dry ash infant formula...
متن کاملDetermination of Antimony (III) in Real Samples by Anodic Stripping Voltammetry Using a Mercury Film Screen-Printed Electrode
This paper describes a procedure for the determination of antimony (III) by differential pulse anodic stripping voltammetry using a mercury film screen-printed electrode as the working electrode. The procedure has been optimized using experimental design methodology. Under these conditions, in terms of Residual Standard Deviation (RSD), the repeatability (3.81 %) and the reproducibility (5.07 %...
متن کاملDetermination of mercury at a dithizone-modified glassy carbon electrode by anodic stripping voltammetry.
متن کامل
Determination of Trace Mercury (Hg(II)) by Anodic Stripping Voltammetry at a Gold Electrode
ronment, the determination of trace Hg(II) is important. Atomic absorpt ion and inductively coupled plasma spectroscopic methods are currently widely used. Many publications on this subject focus on electrochemical methods (anodic and potentiometric stripping voltammetry) at a variety of electrode materials. Glassy carbon, goldplated glassy carbon, screen-printed carbon, platinum (Pt) and gold ...
متن کاملDetermination of carbendazim in soil samples by anodic stripping voltammetry using a carbon fiber ultramicroelectrode.
A method for the determination of carbendazim (MBC) by anodic stripping voltammetry using a carbon fiber ultramicroelectrode was developed. The ultramicroelectrode was made in our laboratory and its electrochemical behavior was characterized by measuring the electrochemical response with a solution of potassium ferricyanide. The optimum parameters used for the determination of MBC are the follo...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Chemistry
سال: 2021
ISSN: ['2090-9063', '2090-9071']
DOI: https://doi.org/10.1155/2021/8888879