Determination of Total Mercury in Solid Samples by Anodic Stripping Voltammetry

نویسندگان

چکیده

The anodic stripping voltammetry (ASV) was investigated to determine total mercury in solid samples using a gold electrode. deposited on the electrode preconcentration step. oxidation peak of irreversible. optimal conditions procedure were found be as follows: 0.05 mol L?1 HCl solution, deposition potential ?0.5 V vs. Ag/AgCl/KCls, time 40 s, and sweep rate 0.04 s?1. Under conditions, current showed linear dependence Hg2+ concentration range from 0.01 0.1 mg l?1. detection limit quantification 4.28 µg 12.98 L?1, respectively. mean recovery relative standard deviation 91.2% 2.4% (n = 9). successfully applied for determining collected Hanoi light bulb warehouse—The Rang Dong Light Source Vacuum Flask JSC. results compared with cold vapor atomic absorption spectrometry (CV-AAS).

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ژورنال

عنوان ژورنال: Journal of Chemistry

سال: 2021

ISSN: ['2090-9063', '2090-9071']

DOI: https://doi.org/10.1155/2021/8888879